MATERIAL SAFETY DATA SHEET

     Spectrum Ethers Pvt. Ltd.

PROPICONAZOLE TECHNICAL

Rasegaon Village, Nashik (M.S.)

Contry: India, Pin-422202
Emergency Phone: 02557 – 228000

1. Product and Company Identification					
									
Product Name	:	Propiconazole Technical		
Chemical Name	:	(2RS,4RS;2RS,4SR)-1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-	
		2-ylmethyl]-1H-1,2,4-triazole		
Chemical Class	:	Triazole fungicides		
Molecular formula	:	C15H17Cl2N3O2		
						
2. Composition / Information on ingredients				
							
Chemical Name		CAS#		Percent or content (w/w)	
Propiconazole		60207-90-1		92.00 %	
Other ingredients		-				8.00%	
					
3. Health Hazards Identification			
						
Toxicity	:   This product is slightly hazardous		
Inhalation	:	Slightly toxic		
Ingestion	:	Slightly toxic		
Skin	:	Mild irritant - skin sensitizer		
Eye	:	Mild irritant		
Sensitization	:	Non-sensitizer to skin		
								
4. First Aid Measures								
									
Eyes	Hold eye open and rinse gently with fresh water for 15-20 minutes. If	
	Irritation persists, consult a medical Physician.		
Skin	Take off contaminated clothing. Wash skin immediately with plenty of	
	Sop & Water for 15-20 minutes.		
Ingestion	Give a large quantity of medical charcoal in plenty of water. Seek medical	
	attention if a large column of concentrate was ingested.	

Inhalation	Move person to fresh air. Give artificial respiration if required and call ambulance. Seek immediate medical assistance.

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5. Fire Fighting Measures

Fire		Not expected to be a fire hazard	
Explosion		None identified	
Suitable Extinguishing		Use water fog, foam, CO2 to extinguish flames.	
Media					
Flammability Properties  Non-flammable, product is combustible	
			
6. Accidental Release Measures			
					
Personal precautions	:	Wear suitable protective clothing, shoes, gloves and goggle.	
In case of spill or leak	:	Control the spill at its source. Control the spill to prevent it from	
		spreading, contaminating soil, or entering sewage and drainage	
		systems or any body of water.	
		Clean the spills immediately. Cover the entire spill with absorbing	
		material and place into compatible disposal container. Scrub area	
		with hard water detergent. Pickup wash liquid with additional	
		absorbent and place into compatible disposal container. Once all	
		material is cleaned up and placed in disposal containers, seal	
		container and arrange for disposition.	
				
7. Handling and Storage				
				
Handling	:	Prevent eating, drinking, tobacco use and cosmetic application in	
		areas. Where there is a potential for exposure to the material.	
		Wash thoroughly with soap and water after handling.	
Storage	:	Keep tightly closed in original labeled container. Keep away from	
		the reach of children. Keep away from foods, drinks and animals	
		feeding stuffs.	
Suitable materials &	:	Aluminum and Stainless steel.	
Coatings					

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Loading & uploading	:	Ambient	
Temperature				
Transport		Ambient	
Temperature				
Specific use		Use  this  product  only  for  plant  protection  under  outdoor	
		conditions.	
		
8. Exposure Controls/Personal Protection		
			
Ingestion	Prevent eating, drinking, tobacco use, and cosmetic application in areas	
	where there is a potential for exposure to the material.	
Eye protection	Where eye contact is likely, use chemical splash goggles. Facilities storing	
	or utilizing this material should be equipped with an eyewash facility and	
	a safety shower.	
Skin Protection	Where contact is likely wear chemical- resistant gloves, coverall, socks	
	And  chemical-resistant  foot  wear.  For  over  head  exposure,  wear	
	chemical-resistant head gear.	
Inhalation	Use approved chemical cartridge respirator with organic vapor cartridges	
	and Pre- filters or a supplied air respirator.	
	
9. Physical and Chemical Properties		
				
Appearance		Transparent amber colour liquid	
Odour		Musty odour	
Melting Point		23°C (glass transition temperature)	
Boiling Point		180 °C (356 °F; 453 K) at 0.1 mmHg [1]	
pH		5.77		
Vapour Pressure		6.7 x10-5Pa at 25°C	
Water solubility		100 mg/l (20oC)	
Relative density		1.282 (20oC)	
Flash Point		233oC	

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10. Stability and Reactivity

Chemical Stability		stable material	
Hazardous Polymerization	Will not occur	
Incompatibilities		Not known	
				
11. Toxicological Information		
						
Acute Oral Toxicity		LD50 (Rats) 300-2000 mg/kg	
Acute Dermal Toxicity	LD50 (Rats) 2,000 mg/kg b.w	
Acute Inhalation		LC50 (rats): 5.13 mg / L air (4 h)	
Eye Irritation		Rabbit: Mild irritant	
Skin Irritant		Rabbit: Mild irritant	
Skin Sensitization		Guinea pig: Sensitizing	
				
12. Ecological Information				
				
Birds	Acute oral LD50 (Japanese quail) 2223 mg/kg bw	
		LC50 (5 d, Japanese quail) >10,000 mg/kg diet	
	Acute oral LD50 (mallard ducks) >2510 mg/kg bw	
		LC50 (5 d, mallard ducks) >5620 mg/kg diet	
Fish	LC50 (96 h) for Rainbow trout 4.3 mg/l,	
			Carp 6.8 mg/l	
Bees	LD50 (oral & contact) >100  g/bee	
	LD50 (contact) >200  g/bee	
				
13. Disposal Considerations				
				
Waste	Disposal	Do not reuse product containers. Dispose of product  containers, waste	
Method		containers and residues according to local, state and federal health and	
		environmental regulations.	

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14. Transport Information

Rail/Road (RID/ADR)

Proper Shipping Name	:	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S	
Class	:	9			
UN No.	:	3082			
Packing Group	:	III			
Sea (IMDG – Code)					
Proper Shipping Name	:	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S	
Class	:	9			
IMDG No.	:	3082			
Packing Group	:	III			
Marine Pollutant	:	Yes			
Air (ICAO/IATA)					
Proper Shipping Name	:	ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S	
Class	:	9			
UN No.	:	3082			
Packing Group	:	III			
				
15. Regulatory Information				
EU- Classification Hazard		Xn	Harmful	
Symbol		N	Dangerous for the environment	
Special Risks (R-Phrases)		22	Harmful if swallowed	
		43	May cause sensitization by skin contact	
		50/53	Very toxic to aquatic organisms, may cause long-term	
			adverse effects in the aquatic environment	
Safety Advice (S- Phrases)		36/37	Wear suitable protective clothing and gloves.	
		46	If swallowed, seek medical advice immediately and	
			show this container or label.	
		60	This material and its container must be disposed of as	
			hazardous waste	
		61	Avoid release to the environment. Refer to special	
			instructions/Safety data sheets.	

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International WHO Toxicity	III	Slightly hazardous
Classification

16. Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall we be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if we have been advised of the possibility of such damages.

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